Understanding the Chemical Requirements of Aggregates in Concrete Production

Aggregates play a crucial role in concrete production, providing the necessary granular materials for its composition. These materials can be natural, manufactured, or recycled, encompassing a variety of options such as gravel, crushed stone, sand, slag, recycled concrete, and geosynthetic aggregates.

Continuation from Previous Articles: This discussion follows our exploration of geometrical and physical requirements in aggregates, building upon the standards set by the European Union (EN – 12620). In this installment, we delve into the chemical requirements, focusing on chloride, sulfur content, and other constituents specified in EN – 12620.

1. Chlorides Content

The concentration of water-soluble chloride ions in concrete aggregates is a critical factor. According to EN 1744-1:1998, clause 7, producers must declare this content upon request. If the chloride ion content is known to be minimal (e.g., 0.01% or lower), this value can be used in concrete chloride content calculations.

2. Sulfur Compounds

2.1 Acid Soluble Sulfate

The acid-soluble sulfate content of aggregates and filler aggregates for concrete, determined per EN 1744-1:1998, clause 12, is categorized and declared according to Table 20.

Category Maximum Value
A X1
B X2

2.2 Total Sulfur

EN 1744-1:1998, clause 11, establishes limits for total sulfur content:

  • 2% S by mass for air-cooled blast furnace slag.
  • 1% S by mass for aggregates other than air-cooled blast furnace slag.

Special precautions apply if pyrrhotite is present, limiting the total sulfur content to 0.1% as S.

3. Other Constituents

3.1 Constituents Affecting Concrete Setting and Hardening

Aggregates with substances altering concrete setting and hardening undergo assessment. EN 1744-1:1998, 15.3 outlines criteria ensuring they do not adversely impact stiffening time or compressive strength.

Organic Matter Determination: EN 1744-1:1998, 15.1 and 15.2 determine organic matter presence, considering humus content and fulvic acids. Lightweight or organic contaminator presence is tested per EN 1744-1:1998, 14.2.

3.2 Constituents Affecting Volume Stability of Air-Cooled Blast Furnace Slag

Air-cooled blast furnace slag aggregates must be free from dicalcium silicate and iron disintegration, as per EN 1744-1:1998, 19.1 and 19.2, respectively.

4. Carbonate Content of Fine Aggregates for Concrete Pavement Surface

Controlling carbonate content in fine aggregates for concrete surface courses is vital. Determination, as specified in EN 196-21:1989, clause 5, and declaration of results following EN 1744-1:1998, ensure compliance.

Answering Common Questions:

1. Importance of Aggregates in Concrete

Aggregates significantly influence concrete properties like workability, durability, strength, weight, and shrinkage. Their composition, shape, and size play a pivotal role.

2. Size of Coarse Aggregate in Concrete Production

Generally, for concrete production, aggregates passing a 20mm sieve and retained on a 12.5mm sieve are preferred.

Conclusion:

Understanding and adhering to these chemical requirements ensures the production of high-quality concrete, meeting European Standards and delivering robust structural performance.

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